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Chemometrics in Spectroscopy Column
  • The Long, Complicated, Tedious, and Difficult Route to Principal Components: Part IV



    Howard Mark and Jerome Workman, Jr. continue their discussion of the derivation of the principal component algorithm using elementary algebra.

    The Long, Complicated, Tedious, and Difficult Route to Principal Components: Part III




    Howard Mark and Jerome Workman, Jr. continue their discussion of the derivation of the principal component algorithm using elementary algebra.

    The Long, Complicated, Tedious, and Difficult Route to Principal Components: Part II



    Howard Mark and Jerome Workman, Jr. continue their discussion of the derivation of the principal component algorithm using elementary algebra.

    The Long, Complicated, Tedious, and Difficult Route to Principal Components: Part I



    In this month's installment, columnists Howard Mark and Jerome Workman, Jr. present the derivation of the principal component algorithm using elementary algebra.

    Addendum to Chemometrics in Spectroscopy




    This column is the continuation of a series (1-5) dealing with the rigorous derivation of the expressions relating the effect of instrument (and other) noise to its effects on the spectra we observe. Our first column in this series was an overview. While subsequent columns dealt with other types of noise sources, the ones listed analyzed the effect of noise on spectra when the noise is constant detector noise (that is, noise that is independent of the strength of the optical signal). Inasmuch as we are dealing with a continuous series of columns, on this branch in the thread of the discussion, we again continue the equation numbering and use of symbols as though there were no break. The immediately previous column (5) was the first part of this set of updates of the original columns.

    What Can NIR Predict?



    Columnists Howard Mark and Jerome Workman, Jr. discuss the application of chemometric methods of relating measured NIR absorbances to compositional variables of samples.

    Corrections to Analysis of Noise: Part I



    Columnists Howard Mark and Jerome Workman, Jr. respond to reader feedback regarding their 14-part column on the analysis of noise in spectroscopy by presenting another approach to analyzing the situation.

    Limitations in Analytical Accuracy, Part II: Theories to Describe the Limits in Analytical Accuracy and Comparing Test Results for Analytical Uncertainty



    In the second part of this series, columnists Jerome Workman, Jr. and Howard Mark continue their discussion of the limitations of analytical accuracy and uncertainty.

    Limitations in Analytical Accuracy, Part I: Horwitz's Trumpet



    September 2006. In the first part of this two-part series, columnists Jerome Workman, Jr. and Howard Mark discuss the limitations of analytical accuracy and uncertainty.

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